姓名： 孙燕琼

邮箱：sunyanqiong@fzu.edu.cn

科研简介

科研：主要从事稀土取代多金属氧簇的合成、结构和性能研究；Ln-Cd异核金属-有机发光材料的设计合成、结构调控和荧光探针性能研究；光致变色材料的合成及结构性能研究、功能性配位聚合物的水热合成及结构性能研究；簇基功能材料的结构化学基础研究。2008年以来先后主持包括国家自然科学基金项目、福建省自然科学基金项目和教育部科技发展中心设立的新教师基金等7余项课题。现以第一作者或通讯作者在Angew Chem Int Ed、ChemCommun、Inorg. Chem.、Dalton、Eur. J. Inorg. Chem.、Cryst. Growth. Des.、CrystEngComm等国际化学学科的重要期刊上发表论文七十多篇。

科研项目

作为课题负责人主持以下项目：

8、国家自然基金面上项目：高核3d-4f异金属簇基多铌氧簇的导向合成、结构调控及性能研究，2019年1月－2023年12月。

7、国家自然基金面上项目：具有荧光探针功能的Eu-Cd异金属配合物的可控合成、荧光识别及应用研究，2015年1月－2016年12月。

6、国家自然青年科学基金：Ln-Cd异核金属有机发光材料的设计合成、结构调控和性能评价， 2011年1月－2013年12月。  
5、福建省面上基金：含硫芳香羧酸水(溶剂)热原位合成、配位组装及性能研究，2013年1月－2016年12月。

4、福建省面上基金：具有荧光探针功能的Ln-Cd异金属配合物的可控合成、结构及荧光识别性能研究，2017年4月-2020年3月。

3、福建省青年科技人才创新项目：基于不同金属簇单元构筑的功能金属－有机空旷材料（2008F3120），2008年8月－2011年9月。  
2、教育部科技发展中心设立的新教师基金：含有软硬配位点硫醚（巯基）羧酸功能配合物的设计合成、结构及光电性能研究（20093514120002），2010年1月－2012年12月。  
1、福州大学科技发展中心育苗基：功能性配体及配合物的设计合成、结构和光电性能研究，2010年1月－2012年12月。

代表性论文：

[48] Yong-Jiang Wang, Lan Yu, Xin-Xiong Li, Yan-Qiong Sun^* and Shou-Tian Zheng^*, Two unprecedented germanoniobate frameworks based on high-nuclearity peanut-shaped {Ge₁₂Nb₃₈} clusters, Inorg. Chem., 2024, 63, 1288-1394.

[47] Zeng-Kui Zhu, Ya-Yun Lin, Rong-Da Lai, Xin-Xiong Li, Yan-Qiong Sun*, Shou-Tian Zheng^* , A series of high-nuclear planar equilateral triangle-shaped {Ln₆(µ₃-OH)₆} cluster encapsulated polyoxoniobates with frequency dependent magnetic property, Chinese. Chem. Lett. 2023，34，107773.

[46] Da-Huan Li, Nian Shi, Yong-Jiang Wang, Ping-Wei Cai, Yan-Qiong Sun^* and Shou-Tian Zheng^*, An organic-inorganic hybrid polyoxoniobate decorated by a Co(III)-amine complex for electrocatalytic urea splitting, Inorg. Chem. Front., 2023, 10, 4789-4796.

[45] Yong-Jiang Wang, Nian Shi, Cai Sun, Yan-Qiong Sun^* and Shou-Tian Zheng^*, Reversible thermochromism and stable resistance switching behaviors based on a Co(III)-complex-linked polyoxoniobate, Inorg. Chem., 2023, 62, 10675-10683.

[44] Rong-Da Lai, Hui-Lin Feng, Yan-Qiong Sun* Xin-Xiong Li and Shou-Tian Zheng^*, A lanthanide–tellurium heterometal encapsulated sandwich-type heteropolyoxoniobate with a 3D pcu-type hydrogen-bonded network, Dalton Trans., 2022, 51, 10571-10577.

[43] Yan-Lan Wu, Yong-Jiang Wang, Yan-Qiong Sun^*, Xin-Xiog Li, and Shou-Tian Zheng^*，Two high-nuclearity isopolyoxoniobates containing {Nb₅₄O₁₅₁}-based helical nanotubes for the decomposition of chemical warfare agent simulants，Chem. Commun., 2022, 58, 3322-3325.

[42] Hao Yu, Yu-Diao Lin, Zheng-Yi Liu, Yan-Qiong Sun^* and Shou-Tian Zheng^*, A 3D indium-containing polyoxoniobate framework based on {In₅Nb₇₁}_n helical pillars, Inorg. Chem., 2022, 61, 8112-8116.

[41] Nian Shi, Yong-Jiang Wang, Xin-Xiong Li, Yan-Qiong Sun^* and Shou-Tian Zheng*, An inorganic Co-containing heteropolyoxoniobate: reversible chemochromism and H₂O-dependent proton conductivity properties, Inorg. Chem. Front., 2021, 8, 5225-5233.

[40] Zhuo-Hao Zhong, Ji-Xin Jing, Yan-Qiong Sun^*, Xin-Xiog Li, and Shou-Tian Zheng^*, Two new 3D tubular polyoxoniobates frameworks based on {SiNb₁₈O₅₄} clusters with proton conduction properties, Inorg. Chem. Comm., 2021, 132, 108813.

[39] Yan-Lan Wu, Zhuo-Hao Zhong, Ping-Xin Wu, Yan-Qiong Sun^*, Xin-Xiong Li, and Shou-Tian Zheng^*, A peanut-like Sb-embedded polyoxoniobate cage for hydrolytic decomposition of chemical warfare agent, Eur. J. Inorg. Chem., 2021, 1505-1509.

[38] Zeng-Kui Zhu, Li-Dan Lin, Jing Zhang, Xin-Xiong Li, Yan-Qiong Sun^* and Shou-Tian Zheng^* , A rare 4-connected a neb-typed 3D chiral polyoxometalate framework based on {KNb₂₄O₇₂} cluster, Inorg. Chem. Front., 2020, 7, 3919-3924; 

[37] Yan-Lan Wu, Yan-Qiong Sun^*, Xin-Xiog Li, and Shou-Tian Zheng^*，A new dimeric isopolyoxoniobate {β-H4Nb52O150} decorated with copper(II)-ethylenediamine for hydrolytic decomposition of chemical warfare agent simulant DMMP, Inorg. Chem. Comm., 2020, 113, 107815.

[36] Zeng-Kui Zhu, Ya-Yun Lin, Li-Dan Lin, Xin-Xiong Li, Yan-Qiong Sun^* and Shou-Tian Zheng^*, A Rare 3D porous inorganic−organic hybrid polyoxometalate framework based on a cubic polyoxoniobate-cupric-complex cage with a high water vapor adsorption capacity, Inorg. Chem., 2020, 59, 11925-11929.

[35] Yan-Lan Wu, Rong-Tao Zhang, Yan-Qiong Sun^*, Xin-Xiong Li, and Shou-Tian Zheng^*, A series of cube-shaped polyoxoniobates encapsulating octahedral Cu₁₂X_m On clusters with hydrolytic decomposition for chemical warfare agents, Front. Chem., 2020, 8, 586009.

[34] Shi-Yu Wu, Yong-Jiang Wang, Ji-Xin Jing, Xin-Xiong Li, Yan-Qiong Sun^* and Shou-Tian Zheng^*, Two organic-inorganic hybrid polyoxotungstogermanates containing organic ligand chelated Fe-Dy heterometallic clusters and frequency dependent magnetic properties, Inorg. Chem. Front., 2020, 7, 498-504

[33] Yong-Jiang Wang, Shi-Yu Wu, Yan-Qiong Sun^*, Xin-Xiong Li, Shou-Tian Zheng^*, Octahedron-shaped three-shell Ln₁₄-substituted polyoxotungsto germanates encapsulating W₄O₁₈ cluster: luminescence and frequency dependent magnetic property，Chem. Commun., 2019, 55,2857-2860.

[32] Zhong Li, Li-Dan Lin, Dan Zhao, Yan-Qiong Sun* and Shou-Tian Zheng^*, A series of unprecedented linear mixed-metal-substituted polyoxometalate trimers: syntheses, structures, luminescence, and proton conductivity properties, Eur. J. Inorg. Chem.，2019, 437-441.

[31] Jin-Hua Liu, Rong-Tao Zhang, Jing Zhang, Dan Zhao, Xin-Xiong Li, Yan-Qiong Sun^* and Shou-Tian Zheng^*, A series of 3D porous lanthanide-substituted polyoxometalate frameworks based on rare hexadecahedral {Ln₆W₈O₂₈} heterometallic caged-shaped clusters, Inorg. Chem., 2019, 58, 14734-14740.

[30] Qing Shi, Shi-Yu Wu, Xing-Tai Qiu, Yan-Qiong Sun^* and Shou-Tian Zheng^*, Three viologen-derived Zn-organic materials: photochromism, photomodulated fluorescence, inkless and erasable prints, Dalton Trans., 2019, 48, 954-963.

[29] Yan-Jie Qi, Yong-Jiang Wang, Xin-Xiong Li, Dan Zhao^*, Yan-Qiong Sun*, Shou-Tian Zheng, Two d¹⁰ Metal−Organic Frameworks as Low-Temperature Luminescent Molecular Thermometers, Cryst. Growth. Des., 2018, 18, 7383-7390.

[28] Xing-Tai Qiu, Qing Shi, De-Quan Zhang, Qing-Feng Lin, and Yan-Qiong Sun*, A Multi-Responsive Cd–Viologen Complex:Photochromism, Photomodulated Fluorescence, and Luminescent Sensing, ChemistrySelect., 2018, 3, 6611–6616.

[27] Yan-Qiong Sun* Qi Liu, Le-Hui Liu, Ling Ding, Yi-Ping Chen, Two 3D nonlinear optical and luminescent lanthanide-organic frameworks with multidirectional helical intersecting channels, New. J. Chem., 2017, 41, 6736-6741.

[26] Ling Ding, Jie-Cen Zhong, Xing-Tai Qiu, Yan-Qiong Sun*, Yi-Ping Chen, Syntheses, structures, photoluminescence and photocatalysis of 2D layered lanthanide-carboxylates with 2, 2′-dithiodibenzoic acid, J. Solid. State. Chem., 2017, 246, 138-144.

[25] Ling Ding, Le-Hui Liu, Qing Shi, Yan-Qiong Sun*, Yong-Jiang Wang, Yi-Ping Chen, Luminescent 3D Lanthanide−Cadmium Heterometal−Organic Frameworks with Chemical Stability and Selective Luminescent Sensing, Inorg. Chem., 2017, 56, 14850−14858.

[24] Le-Hui Liu, Xing-Tai Qiu, Yong-Jiang Wang, Qing Shi, Yan-Qiong Sun*, Yi-Ping Chen, NIR emission and luminescent sensing of a lanthanide–organic framework with Lewis basic imidazole and pyridyl sites, Dalton Trans., 2017, 46, 12106-12113.

[23] Yan-Qiong Sun, Fang Wan, Xin-Xiong Li, Jian Lin, Tao Wu, Shou-Tian Zheng* and Xianhui Bu*, A lanthanide complex for metal encapsulations and anion exchanges, Chem. Commun., 2016, 52, 10125-10128.

[22] Jie-Cen Zhong, Fang Wan, Yan-Qiong Sun*, Yi-Ping Chen Luminescent hybridlanthanidesulfatesandlanthanide sulfonate-carboxylates with 1,10-phenanthroline involving in-situ oxidation of 2-mercaptonbenzoicacid, J. Solid. State. Chem., 2015, 221, 14-20.

[21] Yan-Qiong Sun,* Jie-Cen Zhong, Ling Ding，Yi-Ping Chen，Syntheses, structures, photoluminescence and photocatalysis of chiral 3D Cd( II ) frameworks from achiral mixed flexible ligands by spontaneous resolution，Dalton. Trans., 2015, 44, 11852-11859.

[20] Fang Wan, Li-Xia Qiu, Liang-Liang Zhou, and Yan-Qiong Sun* Yi You，A fluorescent, photochromic and thermochromic trifunctional material based on a layered metal–viologen complex，Dalton. Trans., 2015, 44, 18320–18323.

[19] Qi Liu, Fang Wan, Li-Xia Qiu, Yan-Qiong Sun* Yi-Ping Chen, Four 2D Ln–Cd heterometal–organic coordination polymers based on tetranuclear Ln–Cd oxo-cluster with highly selective luminescent sensing of organic molecules and metal cations, RSC Adv., 2014, 4, 27013- 27021.

[18] Sun Yan-Qiong*, Qi Liu, Liang-Liang Zhou, Chen Yi-Ping, Ln-Cd heterometal organic-inorganic hybrid materials based on diverse Ln-Cd oxo-cluster Chains: syntheses, structures and visible Luminescence, CrystEngComm, 2014, 16, 3986–3993.

[17] Liu Qi, Ge Su-Zhi, Zhong Jie-Cen, Sun Yan-Qiong*, Chen Yi-Ping，Two novel 2D lanthanide-cadmium heterometal-organic frameworks based on nanosized heart-like Ln₆Cd₆O₁₂ wheel-clusters exhibiting luminescence sensing to the polarization and concentration of cations，Dalton. Trans., 2013, 42(18), 6314-6317.

[16] Sun Yan-Qiong*, Liu Qi, Zhong Jie-Cen, Pan Qun-Feng, Chen, Yi-Ping，Unique(3,8)-connected lanthanide arenedisulfonate metal-organic frameworks containing benzimidazole-5,6-dicarboxylicacidco-ligand: Syntheses, structures and luminescence, J. Solid. State. Chem., 2013, 206, 85-90.

[15] Yan-Qiong Sun *, Su-Zhi Ge, Qi Liu, Jie-Cen Zhong, Yi-Ping Chen，A novel 3-D chiral bismuth-organic framework with mixed carboxylate, pyridine and thiolate donors exhibiting a semiconductive property，CrystEngComm, 2013, 15(47), 10188-10192.

[14] Yan-Qiong Sun*, Song Deng, Qi Liu, Su-Zhi Ge, Yi-Ping Chen，A green luminescent 1-D helical tubularb dipyrazol-bridged cadmium(II) complex. A coordination tube included in a supramolecular tube，Dalton. Trans., 2013, 42(29), 10503-10509.

[13] Yan-Qiong Sun, Jin Hu, Han-Hui Zhang, Yi-Ping Chen, Hydrothermal syntheses, structures and characterizations of two luminescent cadmium(II) complexes with p-xylenediphosphonic acid and N-donor ligands, J. Solid. State. Chem., 2012, 186, 189-194.

[12] Yan-Qiong Sun*,  Hong-Xin Mei,  Han-Hui Zhang,  Yi-Ping Chen, Rui-Qing Sun, Unique (3,12)-Connected Inorganic Lanthanide Cluster Polymer Based on Octahedral Hexanuclear Europium Hydroxide Clusters and Sulfate Anions: Synthesis, Structure, and Luminescence, J. Cluster. Sci, 2011, 22, 279-288

[11] Yan-Qiong Sun, Chen Yang, Zhengtao Xu^*, Matthias Zeller and Allen D. Hunter, Networks of Hexagonal Hierarchy from a Self-Similar Tritopic Molecule, Cryst. Growth. Des., 2009, 9, 1663-1665.

[10] Yan-Qiong Sun, Chun-Kwan Tsang, Zhengtao Xu^*, Guo Huang, Jun He, Xiao-Ping Zhou, Matthias Zeller and Allen D. Hunter, CuCN Pillars induce face-to-face π-overlap of anthracene-based thioether molecules within a hybrid coordination Network, Cryst. Growth. Des., 2008, 5, 1468-1470.

[9] Yan-Qiong Sun, Guo-Yu Yang^*, Organic-inorganic hybrid materials constructed from inorganic lanthanide sulfate skeletons and organic 4, 5-imidazoledicarboxylic acid, Dalton. Trans., 2007, 3771-3781.

[8] Yan-Qiong Sun, Jun He, Zhengtao Xu^*, Matthias Zeller, Allen D. Hunter, Centripetal molecules as multifunctional building blocks for coordination networks, Chem. Commun., 2007, 4779-4781.

[7] Yan-Qiong Sun, Jie Zhang* and Guo-Yu Yang, Molecular self-assemblies of a π-conjugated redox-active bipyridinium cation with magnetic dimetallic oxalate-bridged trimeric clusters. Dalton. Trans., 2006, 1685-1690.

[6] Yan-Qiong Sun, Jie Zhang and Guo-Yu Yang^*, A series of luminescent lanthanide -cadmium-organic frameworks with helical channels and tubes, Chem. Commun., 2006, 4700-4702.

[5] Yan-Qiong Sun, Jie Zhang, Guo-Yu Yang^*, Two novel luminescent lanthanide sulfate-carboxylates with an unusual 2-D bamboo-raft-like structure based on the linkages of left- and right-handed helical tubes involving in situ decarboxylation, Chem. Commun., 2006, 1947-1949.

[4] Yan-Qiong Sun, Jie Zhang, Yong-Mei Chen, Guo-Yu Yang^*, Porous lanthanide-organic open frameworks with helical tubes constructed from interweaving triple-helical and double-helical chains, Angew. Chem. Int. Ed., 2005, 44, 5814-5817.

[3] Yan-Qiong Sun, Jie Zhang*, Zhan-Feng Ju and Guo-Yu Yang, 2D Non-interpenetrating transitional metal coordination polymers with large honeycomb-like hexagonal cavities constructed from a carboxybenzyl viologen ligand, Cryst. Growth. Des., 2005, 5, 1939-1943.

[2] Yan-Qiong Sun, Jie Zhang*, Jing-Lin Chen and Guo-Yu Yang, Two copper(II) complexes built from a novel redox-active bipyridinium dimer Ligand and oxalate anions: synthesis, crystal structure and magnetic properties, Eur. J. Inorg. Chem., 2004, 3837-3841.

[1] Yan-Qiong Sun, Jie Zhang*, and Guo-Yu Yang, One- and two-dimensional coordination assemblies of a novel redox-active bipyridinium dimer ligand with magnetic oxalate complexes, Dalton. Trans., 2003, 3634-3638.