孙财
福州大学 化学学院 副教授
福州地区大学城学园路2号
350116
csun@fzu.edu.cn
学历
交换生，兰州大学，化学化工学院 2010.09 - 2011.07
理学学士，应用化学专业，山东大学，海洋学院 2013.06
理学博士，无机化学专业 中国科学院大学，福建物质结构研究所 2018.06
学术经历
博士，中科院物构所 2013.09 - 2018.06
指导老师：王明盛、郭国聪
设计和合成新的光致变色材料（晶态无机-有机杂化体系）
光致变色材料的性能研究（电学和光学的开关性质，电子转移过程）
光致变色材料薄膜的制备
博士后，中科院物构所 2018.07 – 2020.08
合作导师：王明盛、郭国聪
探索光致变色半导体材料的智能器件（光电探测器，光伏器件，传感器，晶体管）
光致变色介电开关材料的研究
光致变色材料的理论计算研究（分子间相互作用和电子转移）
副教授，福州大学 2020.08 – 至今
刺激响应的功能多酸化学（光致变色、电致变色、分子识别、材料改性等）
理论计算研究（分子间相互作用和电子转移）
获得资助
[1] 光致变色材料和智能器件，中国博士后创新人才计划（BX20180304），20万，主持，2018-2020
[2] 室温光致变色介电开关材料的研究，中国博士后面上基金（2018M642580），5万，主持， 2018-2020
[3] 电子转移光致变色半导体的结构设计和导电调制研究，结构化学国家重点实验室优秀青年项目，25万，主持，2019-2020
[4] 无机-有机杂化多铌氧酸簇聚物的光致变色性质的探索，国家青年科学基金项目（22001037）， 24万，主持，2021-2023
[5] 紫精基多铌氧酸簇聚物的光致变色性质的探索，福州大学贵重仪器设备开放测试基金(2021T00，0.5万，主持，2021-2022
[6] 光致变色功能的杂化多铌氧酸簇聚物的性能优化，福州大学科研启动经费（511002），30万， 主持，2021-2022
[7] 光致变色电荷转移复合物的设计合成和导电开关研究，福建省自然科学青年创新项目 （2021J05111），6万，主持，2021-2024
[8] 无机-有机杂化多钽氧酸簇聚物的光致变色性质的探索，结构化学国家重点实验室开放基金， 5万，主持，2022-2024
研究兴趣
分子间相互作用和电子转移的理论计算研究
用于γ和x射线探测器的新材料研究
电子转移过程，刺激响应材料，光致变色材料
发表论文
1. Cai Sun+, Xiao-Qing Yu+, Ming-Sheng Wang,* and Guo-Cong Guo. A Smart Photochromic Semiconductor: Breaking the Intrinsic Positive Relation Between Conductance and Temperatue,Angew. Chem. Int. Ed. 2019, 58(28), 9475-9478.
2. Cai Sun, Ming-Sheng Wang,* and Guo-Cong Guo*. Covalently Bonded Pillared Layered Bromoplumbate with High Thermal Stability: High Capacitance Gain after Photoinduced Electron Transfer, ACS Appl. Mater. Interfaces 2019, 11(34), 30713-30718.
3. Cai Sun, Gang Xu, Xiao-Ming Jiang, Guan-E Wang, Pei-Yu Guo, Ming-Sheng Wang,* and Guo-Cong Guo*, Design Strategy for Improving Optical and Electrical Properties and Stability of Lead Halide Semiconductors, J. Am. Chem. Soc. 2018, 140(8), 2805-2811. (ESI高被引论文; 获十四届福建省自然科学优秀学术论文二等奖)
4. Cai Sun, Ming-Xiu Du, Jian-Gang Xu, Fei-Fei Mao, Ming-Sheng Wang,* and Guo-Cong Guo, A Nanowire Array with Two Types of Bromoplumbate Chains and High Anisotropic Conductane, Dalton Trans. 2018, 47(4), 1023-1026.
5. Cai Sun, Ming-Sheng Wang,* Pei-Xin Li, and Guo-Cong Guo*, Conductance Switch of a Bromoplumbate Bistable Semiconductor by Electron-Transfer Thermochromism, Angew. Chem. Int. Ed. 2017, 56(2), 554-558. (ESI高被引论文)
6. Cai Sun, Ming-Sheng Wang,* Xian-Zhang, Ning-Ning Zhang, Lin-Rong Cai and Guo-Cong Guo*, Viologen-templated bromoplumbate: a new in situ synthetic method and energy gap engineering, CrystEngComm. 2017, 19(31), 4476-4479.
7. Guan-E Wang,+ Cai Sun,+ Ming-Sheng Wang* and Guo-Cong Guo*. Semiconducting crystalline inorganic–organic hybrid metal halide nanochains, Nanoscale, 2020, 12(8), 4771-4789.
8. Xiu-Shuang Xing,+ Cai Sun,+ Lu Liu, Ming-Sheng Wang* and Guo-Cong Guo, Light-Responsive Proton Conductor: Record High Gain of Proton Conductivity Achieved by Photoinduced Electron-Transfer Strategy, CCS Chem. 2021, 3, 50-57.
9. Cai Sun, Chen Yang, Pei-Xin Li, Ming-Sheng Wang,* and Guo-Cong Guo*, Photoswitching Bulk Quadratic Nonlinear-Optical Properties with Record Contrast in a Photochromic Semiconductor, Inorg. Chem. 2021, 60(13), 9278−9281
10. Cai Sun, Ming-Sheng Wang,* and Guo-Cong Guo*, Photochromic Semiconductors with Record-High Dielectric Permittivity Gain at Room Temperature, ACS Appl. Electron. Mater. 2021, 3(8), 3301−3305.
非第一作者论文：
11. Xian Zhang, Ming-Sheng Wang,* Cai Sun, Chen Yang, Pei-Xin Li and Guo-Cong Guo*. Stabilizing and color tuning pyrazine radicals by coordination for photochromism, Chem. Commun. 2016, 52, 7947-7949.
12. Yong Yan, Jun Chen, Ning-Ning Zhang, Ming-Sheng Wang, Cai Sun, Xiu-Shuang Xing, Rong Li, Jian-Gang Xu, Fa-Kun Zheng and Guo-Cong Guo, Grinding size-dependent mechanoresponsive luminescent Cd(II) coordination polymer. Dalton Trans. 2016, 45, 18074.
13. Yu Xiao, Shuai-Hua Wang, Jian-Gang Xu, Cai Sun, Rong Li, Ya-Ping Zhao, Yong Yan, Fa-Kun Zheng and Guo-Cong Guo, An enhanced extended hook method to realize tetranuclear metal clusters embedded in energetic metal–organic framework channels, CrystEngComm., 2016, 18, 5803.
14. Xiu-Shuang Xing, Zi-Wei Chen, Li-Zhen Cai, Cai Sun, Lin-Rong Cai, Ming-Sheng Wang*, Guo-Cong Guo*, An electron-transfer photochromic metal-organic framework (MOF) compound with a long-lived charge-separated state and high-contrast photoswitchable luminescence, RSC Adv., 2016, 6, 24190.
15. Jian-Gang Xu, Cai Sun, Ming-Jian Zhang, Bin-Wen Liu, Xiao-Zhen Li, Jian Lu, Shuai-Hua Wang, Fa-Kun Zheng* and Guo-Cong Guo*, Coordination Polymerization of Metal Azides and Powerful Nitrogen-Rich Ligand toward Primary Explosives with Excellent Energetic Performances, Chem. Mater. 2017, 29, 9725−9733.
16. Ning-Ning Zhang, Cai Sun, Xiao-Ming Jiang, Xiu-Shuang Xing, Yong Yan, Li-Zhen Cai, Ming-Sheng Wang * and Guo-Cong Guo*, Single-component small-molecule white light organic phosphors, Chem. Commun., 2017, 53, 9269.
17. Muxin Yu, Lian Chen*, Feilong Jiang, Kang Zhou, Caiping Liu, Cai Sun, Xingjun Li, Yan Yang, and Maochun Hong*, Cation-Induced Strategy toward an Hourglass-Shaped Cu6I7− Cluster and Its Color-Tunable Luminescence, Chem.Mater. 2017, 29, 8093−8099.
18. Jian-Gang Xu, Shuai-Hua Wang, Ming-Jian Zhang, Cai Sun, Yu Xiao, Rong Li, Fa-Kun Zheng, Guo-Cong Guo, and Jin-Shun Huang, Nitrogen-Rich Tetranuclear Metal Complex as a New Structural Motif for Energetic Materials, ACS Omega, 2017, 2, 346.
19. Lin-Rong Cai, Li-Zhen Cai, Zi-Wei Chen, Cai Sun, Xiu-Shuang Xing, Ming-Sheng Wang*, and Guo-Cong Guo*, Thermochromic and Magnetic Properties of a Copper(II) Coordination Compound, Chin. J. Struct. Chem., 2017, 36, 40-46.
20. Pei-Yu Guo, Cai Sun, Ning-Ning Zhang, Li-Zhen Cai, Meng-Sheng Wang*, Guo-Cong Guo, An Inorganic–Organic Hybrid Photochromic Material with Fast Response to Hard and Soft X-rays at Room Temperature, Chem. Commun. 2018, 54, 4525-4528.
21. Yong-Qin Wei, Cai Sun, Qing-Song Chen, Ming-Sheng Wang* and Guo-Cong Guo*. Significant enhancement of conductance of a hybrid layered molybdate semiconductor by light or heat. Chem. Commun., 2018, 54, 14077-14080.
22. Pei-Yu Guo, Cai Sun, Ning-Ning Zhang, Li-Zhen Cai, Ming-Sheng Wang* and Guo-Cong Guo. Improving coloration time and moisture stability of photochromic viologen–carboxylate zwitterions. New J. Chem., 2018, 42, 15466-15471.
23. Ning-Ning Zhang, Yong-Fang Han, Cai Sun, Ming-Sheng Wang,* and Guo-Cong Guo. Enhanced Photoinduced Electron Transfer and Stability of Diradicals in Neutral Extended Pyridine N-Oxides. J. Phy. Chem. C 2019, 123, 24670-24675
24. Jian Lu, Shuai-Hua Wang, Yan Li, Wen-Fei Wang, Cai Sun, Pei-Xin Li, Fa-Kun Zheng*. Heat-resistant Pb(II)-based X-ray scintillating metal–organic frameworks for sensitive dosage detection via an aggregation-induced luminescent chromophore. Dalton Trans. 2020, 49, 7309-7314.
25. Xiao-Qing Yu, Cai Sun, Bin-Wen Liu, Ming-Sheng Wang* and Guo-Cong Guo. Directed Self-Assembly of Viologen-based 2D Semiconductors with Intrinsic UV–SWIR Photoresponse after Photo/thermo Activation. Nat. Commun. 2020, 11, 1179.
26. Hui Jiang, Cai Sun, Cao-Ming Yu, Ming-Sheng Wang,* and Guo-Cong Guo*. Broadband Photoresponsive Bismuth Halide Hybrid Semiconductors Built with pi-Stacked Photoactive Polycyclic Viologen. Inorg. Chem. 2021, 60, 5538-5544.
27. Yu-Diao Lin, Rui Ge, Chong-Bin Tian, Cai Sun, Yan-Qiong Sun, Qing-Xin Zeng,* Xin-Xiong Li* and Shou-Tian Zheng, 3d–4f Heterometallic cluster incorporated polyoxoniobates with magnetic properties. Chem. Commun. 2021, 57, 8624-8627.
28. Yu-Diao Lin, Zeng-Kui Zhu, Rui Ge, Hao Yu, Zhong Li, Cai Sun, Yan-Qiong Sun, Xin-Xiong Li *ab and Shou-Tian Zheng* Proton conductive polyoxoniobate frameworks constructed from nanoscale {Nb68O200} cages. Chem. Commun. 2021, 57, 4702-4705.
29. Shuang Peng, Yan-Jie Qi, Xin-Hao Li, Cai Sun, Ling-Yun Li, Xin-Xiong Li,* Shou-Tian Zheng and Qichun Zhang. Two isomeric zeolite-like metal–organic frameworks with mechanically responsive luminescence emission and gas adsorption properties. CrystEngComm 2021, 23, 5753-5757.
30. Ping-Xin Wu, Rong-Da Lai, Rui Ge, Cai Sun, Guo-Qiang Wang, Xin-Xiong Li,* and Shou- Tian Zheng*. A Tellurium-Substituted Heteropolyniobate with Unique π−π Stacking and Ionic Conduction Property. Inorg. Chem. 2021, 60, 6162-6166.
31. Hui-Ping Xiao, Rong-Tao Zhang, Zhong Li, Yu-Feng Xie, Min Wang, Yi-Da Ye, Cai Sun, Yan-Qiong Sun, Xin-Xiong Li,* and Shou-Tian Zheng. Organoamine-Directed Assembly of 5p−4f Heterometallic Cluster Substituted Polyoxometalates: Luminescence and Proton Conductio Properties. Inorg. Chem. 2021, 60, 13718-13726.